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Cornell University

Goodge Electron Microscopy (GEM) Group

Advanced electron microscopy for materials innovation

Research

Our group’s research is driven by a desire to understand how the properties of new materials arise from their atomic architecture, serving the broader goal of on-demand design of novel quantum materials for future technological applications. Functional properties such as multiferroicity, magnetoresistance, and high-temperature superconductivity will be the foundation of next-generation information and energy technologies: state-of-the-art electron microscopes grant us the ability to directly observe and quantify the detailed atomic configurations that define these behaviors.

From superconductors and magnets to catalysts and thermoelectrics, insights to atomic structure, chemistry, and bonding help us better understand exotic or functional materials from their most fundamental building blocks and translate this understanding to improved materials design. These compounds and devices in turn lay the groundwork for technologies ranging from next-generation computation to energy generation and storage to infrastructure. We are particularly interested in seeing things for the first time, whether it’s a newly discovered compound or a new region of phase space (e.g., in situ temperature, fields, or other stimuli), and are continually working to push the limits of what we can study in the electron microscope through both hardware and software developments.

Our research is built on strong collaborations with experts across the theory, synthesis, and measurement of quantum materials. We bridge fields of engineering, physics, materials science, and chemistry to look for creative solutions to complex problems and fundamental questions. Some current projects and topics are highlighted below, but the best way to find out what we’re currently excited about is to get in touch!

Pushing the limits of high resolution electron microscopy

We are always seeking experimental and analytical methods to afford new and meaningful insights. Our expanding capabilities allow us to ask bolder and deeper questions about the materials we study, while every material system pushes us to better and more ambitious experimental design.

Left: a side-entry TEM sample holder which looks like thin metal rod with electronic and mechanical connection. Center: two traces of sample position over time showing a long strain line in grey for a traditional holder and a shorter line in blue labelled "CVT cryo holder". Right: an atomic-resolution ADF image and false-color elemental map of the interface between two square lattices.

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High-temperature and unconventional superconductors

Motivated by both fundamental curiosity and the promise of revolutionary technologies, materials physicists have been working to understand superconductors for well over a century, with interest further exploding following the 1986 discovery of high-temperature superconductivity in copper oxides (cuprates). We investigate new superconductors at the atomic scale, working to understand how subtle changes in parameters such as bond angles or electronic structure can enhance or suppress its emergence. We try to disentangle intrinsic and extrinsic contributions to macroscopic properties, seeking to bridge comprehensive understanding within and between superconducting families.

Left: an image of the atomic lattice in a thin film of infinite-layer nickelate oxide on top of strontium titanate. Right: four electron energy loss spectra showing the characteristic oxygen K edge, with an arrow pointing to a small should that increases in intensity with high doping concentration.

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Quantum magnets

Dynamically tunable properties such as magnetic textures have many potential applications for next-generation information and communication technologies ranging from spintronics to broadband resonators. In many materials, however, these properties are defined by subtle changes in atomic configurations or valence. With local access to the lattice and electronic structure, we leverage STEM techniques to understand how order and disorder across length scales can define macroscopic functionalities.

Left: atomic-resolution STEM image of an intercalated van der Waals material with an overlaid atomic model. A yellow arrow point to a small region where ordered intercalants are missing from the lattice. Right: a large field-of-view Lorentz TEM image showing horizontal stripes of mixed dark and bright contrast. Some stripes are also bent.

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Materials design and engineering

We collaborate with leading synthesis and theory groups around the world to try and better understand and design new quantum materials by engineering their lattice chemistry or geometry. For example, epitaxial strain imparted by atomic-layer controlled thin film growth is a powerful way to tune materials properties, but can lead to unexpected yet important effects at the substrate-film interface or through the formation of secondary phases. Often, such effects are only visible through advanced local probes, making STEM a cornerstone capability in these collaborative team efforts.

Two images each showing interfaces between different materials. The left shows an interface between crystalline silicon with visible dumbbells and niobium with small regions of atomic alignment. The right image shows highly crystalline layered curate structure on top of niobium, with a several nanometer dark gap between them.

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